Complies with Hazard Communication Standard, as revised (HCS) 29 CFR 1910.1200 and the International Chemical Safety Hazards of the Global Harmonizing System (GHS)

 

1. IDENTIFICATION (CHEMICAL PRODUCT AND MANUFACTURER’S INFORMATION)

Manufacturer: Creator's Way Mission (DSA Re-Paints), 249 West 29th Street, S. Tucson, Arizona P.C. 85713

 

Product Trade Name: Life Cycle Products including “LandMark,” "Grafitti Gone" and "Bulk Blended" Products

 

Revision: 01 / 2016

 

Emergency Telephone: 7:00 AM – 4:30 PM MST Monday-Friday (520) 917-3131

 

Chemical Family: Modified Acrylic Hybrid Emulsion Latex Paint.

Use: Architectural Protective Coating Related Material

2. HAZARD(S) IDENTIFICATION

This material is a water based product containing a minimum of 50% post-consumer materials and does not pose any fire hazard or immediate health hazard when handled in accordance to stated guidelines on the following sections. Review the listed information involving material handling and risk of exposures.

 

Hazard Statement: Generally, the material is Non-Hazardous. However, may cause mild eye and skin irritation. Acute toxicity, maybe harmful if swallowed – Category 5

                              

 

GHS CLASSIFICATION:

Acute Toxicity Oral – Category 5

Acute Toxicity Dermal – Category 5

Acute Toxicity Inhalation – Category 5   

Skin Irritation: Reversible, may cause slight irritation – Category 3                                          

Eye Irritation: Reversible, may cause mild eye irritation – Category 2B   

 

Chronic Effects / Carcinogenetic: This product or any of its ingredients present at < 0.1-0.5% in NOT listed as a carcinogen or suspected carcinogen by NTP, IARC, or OSHA

Precautionary Statement:

Wash thoroughly after handling, wash face, hands and any exposed skin after handling to avoid any mild irritation.

Get medical attention if skin irritation persistently occurs.

Do not breathe mist/vapors, avoid breathing odor and wear protective mask if irritation persists.

Keep container tightly closed after using the material.

Store container tightly closed in cool/well-ventilated place to avoid spills and leaks.

Wear protective gloves and eye/face protection (safety glasses/goggles) to minimize any form eye and skin irritation.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Chemical Name	CAS Reg. No.	Weight %
3-Iodo-2-propynyl butyl carbamate	55406-53-6	< 0.006%
Butane-1,3-diol	107-88-0	< 0.010%
Xylene	1330-20-7	< 0.020%
Alcohols, tallow ethoxylated	61791-28-4	<0.020%
2-Amino-2Propyl 1-Propanol	174-68-5	< 1.000%
2-Butoxy Ethanol	111-76-2	< 3.00%
Titanium Dioxide	13463-67-7	<5.0-10.0%
Zinc Oxide	1314-13-2	<0.5-1%
Polyurethane Polymer	Proprietary	<3.000%
Acrylic Polymer Mixture	Proprietary	50-60%

 

If CAS Registration Number is listed “Proprietary”, the specified chemical has been declared as a TRADE SECRET.

4. FIRST AID MEASURES

Eye Contact: If affected eyes, flush with plenty of water for at least 10 minutes. If irritation persists, seek medical attention.

Inhalation: None known effects.

Injestion: If ingested safely induce vomiting and seek physician.

Skin Contact: Wash with plenty of water, and soap affected areas. If irritation persists, seek medical attention.

5. FIRE FIGHTING AND REACTIVITY

Hazardous Polymerization: Will not occur

Hazardous Thermal Decomposition: May yield Acrylic Polymers

Suitable extinguishing media: Foam, extinguishing powder, carbon dioxide, water fog. In case of fire, cool endangered containers with water fog.

Unsuitable extinguishing media: High pressure water jet.

Specific hazards in case of fire: None are known.

Special protective equipment and precaution for fire fighters: For fires in enclosed areas, wear self-contained breathing apparatus. Do not inhale combustion gases.

6. ACCIDENTAL RELEASE MEASURE

Personal Precautions:

DO NOT eat, drink or smoke while cleaning up. Wear protective clothing, safety glasses and impervious gloves (e.g., neoprene gloves). Ensure adequate ventilation. Avoid all sources of ignition, hot surfaces and open flames.

Environmental Precautions:

DO NOT dispose any liquid portion to any drains leading to the city sewer, and conduct preventive measures to avoid potential spills in the future.

Methods for Clean-Up:

If accidentally released or spilled, immediately wipe, scrape or soak up with inert material (e.g. sand, silica gel, saw dust, and common universal binder), and put in designated container for disposal.

Methods for Containment:

Use an approved container for waste disposal, dried and disposed in accordance to HAZMAT disposal guidelines.

7. HANDLING AND STORAGE

Precautions for Safe Handling:

Avoid contact with eyes. Avoid prolonged repeated skin contact and breathing mists/vapors. Keep container tightly closed, and practice safe handling techniques on lifting. Stir well before using.

Eye and Face Protection: Wear safety glasses with side shields. Use splash resistant goggles for varying wind conditions.

Skin Protection: For prolonged or repeated skin contact wear standard latex gloves.

Work Conditions: Ensure proper air ventilation to avoid concentration build-up

Keep away from children.

Conditions for safe storage, including incompatibilities:

Store at room temperature, and avoid freezing 0 °C / 32 °F and above 100 °C / 212 °F

The product is designed to be used “AS-IS”. Do not intermix with any un-approved material.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Limits:

Chemical Name	CAS Reg No.	ACGIH (TLV/TWA)	OSHA (PEL/TWA)
3-Iodo-2-propynyl butyl carbamate	55406-53-6	No values found	No values found
Butane-1,3-diol	107-88-0	< 20 ppm	< 50 ppm
Xylene	1330-20-7	< 100 ppm	< 100 ppm
Alcohols, tallow ethoxylated	61791-28-4	10 mg/m³	10 mg/m³
2-Amino-2Propyl 1-Propanol	174-68-5	10 mg/m³	10 mg/m³
2-Butoxy Ethanol	111-76-2	< 20 ppm	< 50 ppm
Titanium Dioxide	13463-67-7	10 mg/m³	10 mg/m³
Zinc Oxide	1314-13-2	10 mg/m³	10 mg/m³
Polyurethane Polymer	Proprietary	No values found	No values found
Acrylic Polymer Mixture	Proprietary	No values found	No values found

PEL-OSHA Permissible Exposure Limit; TLV –ACGIH Threshold Limit Value – TWA Time Weighted Average

OSHA revoked the Final Rule Limits of January 19, 1989 in response to the 11^th Circuit Court of Appeals decision (AFL-CIO v. OSHA effective June 30,1993. See 29 CFR 1910.1000 (58 FR 35338)

Appropriate Engineering Controls:

Local exhaust ventilation may be necessary to control air contaminants to their exposure limits. The use of local ventilation is recommended to control emissions near the source. Provide mechanical ventilation for confined spaces. Use explosion-proof ventilation equipment.

Individual protection measures, such as personal protective equipment:

Respiratory protection:

Wear an approved respiratory equipment if ventilation is inadequate.

Eye protection:

Safety glasses with side shields or chemical goggles must be worn.

Skin protection:

If prolonged or repeated skin contact is likely, latex gloves should be worn or any chemical resistant gloves.

General safety measures:

Hand and/or face should be washed before breaks at the end of shift. Avoid contact with skin and eyes. Good personal hygiene practices should always be followed.

9. PHYSICAL AND CHEMICAL PROPERTIES

BOILING POINT – 275 deg. F

FLASH POINT / NON COMBUSTIBLE > 300 deg. F

VAPOR PRESSURE (20 C) (MM HG): 8 MBAR VAPOR DENSITY (AIR=1):

FREEZING POINT: 0 °C; 32 °F

PHYSICAL STATE: liquid various colors

ODOR: light odor, latex paint

pH: 8.0-9.5

EVAPORATION RATE (BUTYL ACETATE=1): <1.0 Water

Specific Gravity: 1.20 – 1.40

 

VOC (G/L): < 250 grams / liter (Material & Coating VOC) SCAQMD Approved Levels

10. STABILITY AND REACTIVITY

Chemical stability: No decomposition, avoid extreme heat above 212 deg. F

Possibility of hazardous reactions: None are known. The product is chemically stable

Conditions to avoid: Heat, sparks, flame and build-up of static electricity.

Materials to avoid: Metal salts.

Hazardous decomposition products: Carbon Dioxide, Carbon Monoxide, Hydrocarbons

11. TOXICOLOGICAL INFORMATION

Primary routes of exposure:

Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases.

 

Acute Toxicity/Effects:

Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact. Virtually nontoxic by inhalation. Ingestion may cause gastrointestinal disturbances. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition.

 

Oral:

Type of value: LD50

Species: rat

Value: > 2,000 - 10,000 mg/kg

Inhalation:

Type of value: ATE

Value: > 5 mg/l

Exposure time: 4 h

Determined for mist

 

Dermal:

Type of value: ATE

Value: > 5,000 mg/kg

 

Assessment other acute effects:

Assessment of STOT single

Based on the available information there is no specific target organ toxicity to be expected after a single exposure.

 

Irritation / corrosion:

Assessment of irritating effects: Not irritating to eyes and skin. May cause mechanical irritation. If the product adheres to skin, irritation may occur when it dries. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition.

 

Skin:

Species: rabbit

Result: non-irritant

Method: OECD Guideline 404

 

Eye:

Species: rabbit

Result: non-irritant

Method: OECD Guideline 405

 

Sensitization:

Assessment of sensitization: The product contains a mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one (3:1) (CAS-No.:55965-84-9). The substance may cause sensitization of the skin in particularly sensitive individuals. Based on our experience and the information available, no adverse health effects are expected if handled as recommended with suitable precautions for designated uses.

 

Aspiration Hazard:

Not applicable

 

Chronic Toxicity/Effects

 

Repeated dose toxicity:

Assessment of repeated dose toxicity: No adverse effects were observed after repeated exposure in animal studies. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition.

 

Genetic toxicity:

Assessment of mutagenicity: The substance was not mutagenic in bacteria. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition.

 

Carcinogenicity:

Assessment of carcinogenicity: The whole of the information assessable provides no indication of a carcinogenic effect.

Reproductive toxicity:

Assessment of reproduction toxicity: Not expected to cause reproductive toxicity (based on composition).

 

Teratogenicity:

Assessment of teratogenicity: The data available for an assessment of the effect of the substance on developmental toxicity are not sufficient for a proper evaluation.

 

Experiences in humans:

According to experience, the product is considered to be harmless to health if used in the correct manner.

 

Other Information:

Based on our experience and the information available, no adverse health effects are expected if handled as recommended with suitable precautions for designated uses. The statement was derived from products of similar composition.

 

Symptoms of Exposure:

No significant symptoms are expected due to the non-classification of the product.

12. ECOLOGICAL INFORMATION

Toxicity

 

Toxicity to fish:

LC50 (96 h) > 100 mg/l, Brachydanio rerio (OECD Guideline 203, static)

 

Aquatic invertebrates:

EC50 (48 h) > 100 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)

 

Aquatic plants:

EC50 (72 h) > 100 mg/l, Scenedesmus subspicatus (OECD Guideline 201)

Nominal concentration.

 

Microorganisms/Effect on activated sludge

 

Toxicity to microorganisms

DIN EN ISO 8192-OECD 209-88/302/EEC,P. C activated sludge, domestic/EC20 (0.5 h): > 100 mg/l

 

The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations.

 

Persistence and degradability

 

Assessment biodegradation and elimination (H2O)

The product can be virtually eliminated from water by abiotic processes e.g. adsorption onto activated sludge.

 

Elimination information

> 70 % DOC reduction (OECD 302B; ISO 9888; 88/302/EEC,part C) Easily eliminated from water.

 

Bio accumulative potential

 

Bioaccumulation potential

Based on its structural properties, the polymer is not biologically available. Accumulation in organisms is not to be expected.

 

Mobility in soil

Assessment transport between environmental compartments

No data available.

 

Additional information

Absorbable organically-bound halogen (AOX): No data available.

Other Eco toxicological advice: Do not release untreated into natural waters. At the present state of knowledge, no negative ecological effects are expected.

Ecological data are determined by analogy.

13. DISPOSAL CONSIDERATION

Waste disposal of substance:

 

Product is suitable for burning in an enclosed, controlled burner for fuel value or disposal by supervised incineration. Such burning may be limited by local regulation. The product is suitable for processing at an appropriate government waste disposal facility. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal.

 

Container disposal:

Dispose of in a licensed facility. Recommend crushing, puncturing or other means to prevent unauthorized use of used containers.

14. TRANSPORT INFORMATION

This product is not regulated for shipping either by ground or by air.

Land transport

USDOT

Not classified as a dangerous good under transport regulations

Class 55

 

Sea transport

IMDG

Not classified as a dangerous good under transport regulations

 

Air transport

IATA/ICAO

Not classified as a dangerous good under transport regulations

15. REGULATORY INFORMATION

US Regulatory Information

CERCLA INFORMATION (40CFR302.4) The release of this material to air, land, or water are not reportable to the National Response Center under the Comprehensive Response, Compensation, and Liability Act or to any other local agencies.

 

CLEAN AIR ACT 

 

CLEAN WATER ACT

 

SARA (311,312) This product does not contain any hazardous chemical under 29CFR 1910.1200, and therefore is not covered by Title III of SARA

 

SARA (313) This product does not contain any hazardous chemicals under the reporting requirement of Section 313 of Title III of the Superfund Amendments (40CFR372)

 

CALIFORNIA PROPOSITION 65: This product does not contain any intentionally-added ingredient covered by the California “Safe Drinking Water and Toxic Reinforcement Act of 1986” .

16. OTHER INFORMATION

This information is offered in good faith, Acrylatex Coatings & Recycling, Inc., disclaims any warranty, liability or any injury that may result to the inappropriate or misuse of the material other than as intended for the use of the product. It is the responsibility of the user to examine the product, and ensure all applicable laws and regulations are met at all levels from city, county, state, and federal guidelines in terms of handling, safety, and disposal.

 

All data reported are typical values, and as not as product specifications, see Technical Data Sheet for more detailed information or contact us for specific questions. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable.

 

HMIS:
Flammability	0	Reactivity	0	Health	1
NFPA:
Flammability	0	Reactivity	0	Health	1